THE CHEMISTRY OF GARDEN CROPS

A Consideration of the chemistry of the crops that engage attention in this country will afford an explanation of one great difference between farming and gardening. And this difference should be kept in mind by all classes of cultivators as the basis of



operations in tillage, cropping, and the order and character of rotations. The first thing to discover in the cropping of a farm is the kind of vegetation for which the land is best adapted to insure, in a run of seasons, fairly profitable results. If the soil is unfit for cereals, then it is sheer folly to sow any more corn than may be needful for convenience, as, for example, to supply straw for thatching and litter, and oats for horses, to save cost of carriage, &c. On large farms that are far removed from markets it is often necessary to risk a few crops that the land is ill fitted for, in order to satisfy the requirements of the homestead, and to save the outlay of money and the inconvenience of hauling from distant markets. But everywhere the cropping must be adapted to the soil and the climate as nearly as possible, both to simplify operations and enlarge to the utmost the chances of success. In the cropping of a garden this plain procedure cannot be followed. We are compelled certainly to consider what the soil and climate will especially favour amongst garden crops, but, notwithstanding this, the gardener must grow whatever the household requires. He may have to grow Peas on a hot shallow sand; and Potatoes and Carrots on a cold clay; and Asparagus on a shallow bed of pebbles and potsherds. To the gardener the chemistry of crops is a matter of great importance, because he cannot restrict his operations to such crops as the land is particularly adapted for, but must endeavour to make the land capable of carrying more or less of all the vegetables and fruits that find a place in the catalogue of domestic wants. That he must fail at certain points is inevitable; nevertheless his aim will be, and must be, of a somewhat universal kind, and a clear idea of the relations of plants to the soil in which they grow will be of constant and incalculable value to him. We are bound to say at the outset that a complete essay on the chemistry of vegetation is not our purpose. We are anxious to convey some useful information, and to kindle sufficient interest to induce those who have hitherto given but slight attention to this question to inquire further, with a view to get far beyond the point at which we shall have to quit the subject. Plants consist of two classes of constituents--the Inorganic, which may be called the foundation; and the Organic, which may be considered the superstructure. With the former of these we are principally concerned here. A plant must derive from the soil certain proportions of silica, lime, sulphur, phosphates, alkalies, and other mineral constituents, or it cannot exist at all; but, given these, the manufacture of fibre, starch, gum, sugar, and other organic products depends on the action of light, heat, atmospheric air, and moisture, for the organic products have to be created by chemical (or vital) action within the structure, or, as we sometimes say, the tissues of the plant itself. To a very great extent the agencies that conduce to the elaboration of organic products are beyond our control (though not entirely so), whereas we can directly, and to a considerable degree, provide the plant with the minerals it more particularly requires; first, by choosing the ground for it, and next by tilling and manuring in a suitable manner. A clay soil, in which, in addition to the predominating alumina, there is a fair proportion of lime, may be regarded as the most fertile for all purposes; but we have few such in Britain, our clays being mostly of an obdurate texture, retentive of moisture, and requiring much cultivation, and containing, moreover, salts of iron in proportions and forms almost poisonous to plants. But there are profound resources in most clays, so that if it is difficult to tame them, it is also difficult to exhaust them. Hence a clay that has been well cultivated through several generations will generally produce a fair return for whatever crop may be put upon it. Limestone soils are usually very porous and deficient of clay, and therefore have no sustaining power. Many of our great tracts of mountain limestone are mere sheep-walks, and would be comparatively worthless except for the lime that may be obtained by burning. On the other hand, chalk, which is a more recent form of carbonate of lime, is often highly productive, more especially where, through long cultivation, it has been much broken up, and has become loamy through accumulation of humus. Between the oldest limestone and the latest chalk there are many intermediate kinds of calcareous soils, and they are mostly good, owing to their richness in phosphates, the products of the marine organisms of which these rocks in great part, and in some cases wholly, consist. For the growth of cereals these calcareous soils need a certain proportion of silica, and where they have this we see some of the finest crops of Wheat, Trifolium, Peas and Beans in these islands. If we could mix some of our obdurate clays with our barren limestones, the two comparatively worthless staples would probably prove remarkably fertile. Although this is impossible, a consideration of the chemistry of the imaginary mixture may be useful, more especially to the gardener, who can in a small way accomplish many things that are impracticable on a great scale. Sandy soils are characterised by excess of silica, and deficiency of alumina, phosphates and potash. Here the mechanical texture is as serious a matter as it is in the case of clay. The sand is too loose as the clay is too pasty, and it may be that we have to prevent the estate from being blown away. It is especially worthy of observation, however, that sandy soils are the most readily amenable of any to the operation of tillage. If we cannot take much out of them, we can put any amount into them, and it is always necessary to calculate where the process of enrichment is to stop. It is not less worthy of observation that sandy soils can be rendered capable of producing almost every kind of crop, save cereals and pulse, and even these can be secured where there is some basis of peat or loam or clay with the sand. The parks and gardens of Paris, Versailles, and Haarlem are on deep sands that drift before the wind when left exposed for any length of time with no crop upon them; and not only do we see the finest of Potatoes and the most nutritious of herbage produced on these soils, but good Cauliflowers, Peas, Beans, Onions, fruits, and big trees of sound timber. Garden soils usually consist of loam of some kind, the consequence of long cultivation. Natural loams are the result of the decay and admixture of various earths, and they are mostly of a mellow texture, easily worked and highly productive. They are, as a rule, the best of all soils, and their goodness is in part due to the fact that they contain a little of everything, with no great predominance of any one particular earth. Cultivation also produces loam. On a clay land we find a top crust of clayey loam, and on a lime or chalk land a top crust of calcareous loam. Where cultivation has been long pursued the staple is broken and manures are put on, and the roots of plants assist in disintegration and decomposition. Thus there is accumulation of humus and a decomposition of the rock proceeding together, and a loam of some sort is the result. Hence the necessity of caution in respect of deep trenching, for if we bury the top soil and put in its place a crude material that has not before seen daylight, we may lose ten years in profitable cropping, because we must now begin to tame a savage soil that we have been at great pains to bring up, to cover a stratum of a good material prepared for us by the combined operations of Nature and Art during, perhaps, several centuries. But deep and good garden soils may be safely trenched and freely knocked about, because not only does the process favour the deep rooting of the plants, but it favours also that disintegration which is one of the causes of fertility. Every pebble is capable of imparting to the soil a solution--infinitesimal, perhaps, but not the less real--of silica, or lime, or potash, or phosphates, or perhaps of all these; but it must be exposed to light and air and moisture to enable it to part with a portion of its substance, and thus it is that mechanical tillage is of the first importance in all agricultural and horticultural operations. The principal inorganic or mineral constituents of plants are potash, soda, lime, iron, phosphorus, sulphur, chlorine, and silica. Clays and loams are generally rich in potash, sulphur, and phosphates, but deficient in soluble silica and lime. Limestone and chalk are usually rich in lime and phosphates, but deficient in humus, silica, sulphur, and alkalies. Sandy soils are rich in silica, but are generally poor in respect of phosphates and alkalies. Therefore, on a clay or loam, farmyard manure is invaluable, because it contains ingredients that all crops appreciate, and also because it is helpful in breaking up the texture of the soil. The occasional application of lime also is important for its almost magical effect on garden soil that has been liberally manured and heavily cropped for a long term of years. Calcareous soils are greatly benefited by a free application to them of manure from the stable and cow-byre; but as a rule it would be like carrying coals to Newcastle to dress these soils with lime. Clay may be put on with advantage; and nothing benefits a hot chalky soil more than a good dose of mud from ponds and ditches, which supplies at once humus, alumina, and silicates, and gives 'staple' to the soil, while preventing it also from 'burning.' In the manuring of sandy soils great care is requisite, because of their absorbing power. In the bulb-growing districts of Holland, manure from cowsheds is worth an enormous price for digging into loose sand for a crop of Potatoes, to be followed by bulbs. Sandy soils are generally deficient in phosphates and alkalies; hence it will on such soils be frequently found that kainit (a crude form of potash) and superphosphate of lime will conjointly produce the best results, more especially in raising Potatoes, Onions, and Carrots, which are particularly well adapted for sandy soils. Probably one of the best fertilisers is genuine farmyard manure from stall-fed cattle, for it contains phosphates, alkalies, and silicates in available forms. For similar reasons Peruvian Guano is often useful on such soils. Artificial manure should be selected with a view to correct the deficiencies of the soil, and to satisfy the requirements of the crops to be grown on it. While we have thus dealt principally with the Inorganic or mineral constituents of plants, and the way in which the deficiencies of the soil in respect of any of them may be supplied by artificial applications, we must not ignore the other class of constituents, the Organic. These are supplied almost entirely from the atmosphere itself, though, to a limited extent, the presence in the soil of humus or vegetable matter contributes also. Yet this latter, as seen in the case of land heavily dressed with farmyard or stable manure, vegetable refuse, &c, exercises important functions in other directions. Not only are mineral constituents, in forms available for assimilation, supplied, but soils so treated derive peculiar advantages as regards their mechanical state and improved physical conditions, chiefly in respect of retention of moisture, warmth, &c. Thus, sandy soils, which are very apt, through poverty in humus, to lose their moisture readily and to 'burn,' are rendered more retentive of moisture and fertilising constituents by the use of farmyard manure, &c., and have more 'staple' or substance given to them, while heavy, tenacious clays are opened out, lightened, and rendered more amenable to the influences of drainage, aeration, &c., and so become less cold and inactive. For the present purpose the principal garden crops may be grouped in two classes, in accordance with their main characteristics and the predominance of certain of their mineral elements. The figures given on the following page show the average percentage proportions of the several minerals in the ashes of the different plants. In Class I. Phosphates and Potash predominate. This class consists of the less succulent plants, and includes the following: The Pea: containing, in 100 parts of the ashes, phosphates, thirty-six; potash, forty. Bean: phosphates, thirty; potash, forty-four. Potato (tubers only): phosphates, nineteen; potash, fifty-nine; soda, two; lime, two; sulphuric acid, six. Parsnip: phosphates, eighteen; potash, thirty-six; lime, eleven; salt, five. Carrot: phosphates, twelve; potash, thirty-six; soda, thirteen; sulphuric acid, six. Jerusalem Artichoke: phosphates, sixteen; potash, sixty-five. In Class II. Sulphur, Lime and Soda Salts are predominant. This class consists of the more succulent plants, and includes the following: Cabbage: containing, in 100 parts of the ashes, phosphates, sixteen; potash, forty-eight; soda, four; lime, fifteen; sulphuric acid, eight. Turnip: phosphates, thirteen; potash, thirty-nine; soda, five; lime, ten; sulphuric acid, fourteen. Beet: phosphates, fourteen; potash, forty-nine; soda, nineteen; lime, six; sulphuric acid, five. As a matter of course, Lentils and other kinds of pulse agree more or less with Peas and Beans in the predominance of phosphates and potash. So, again, all the Brassicas, whether Kales, Cauliflower, or whatever else, agree nearly with the Cabbage in the prominent presence of lime and sulphur; ingredients which fully account for the offensive odour of these vegetables when in a state of decay. Fruits as a rule are highly charged with alkalies, and are rarely deficient in phosphates; moreover, stone-fruits require lime, for they have to make bone as well as flesh when they produce a crop. As regards the alkalies, plants appear capable of substituting soda for potash under some circumstances, but it would not be prudent for the cultivator to assume that the cheaper alkali might take the place of the more costly one as a mineral agent, for Nature is stern and constant in her ways, and it can hardly be supposed that a plant in which potash normally predominates can attain to perfection in a soil deficient in potash, however well supplied it may be with soda. The cheaper alkali in combination as salt (chloride of sodium) may, however, be usually employed in aid of quick-growing green crops; and more or less with tap-roots and Brassicas. Salt, too, is very useful in a dry season by reason of its power of attracting and retaining moisture. As regards Potatoes, it is worthy of observation that they contain but a trace of silica, and yet they generally thrive on sand, and in many instances crops grown on sand are free from disease and of high quality, although the weight may not be great. The mechanical texture of the soil has much to do with this; and when that is aided by a supply of potash and phosphates, whether from farmyard manure or artificials, sandy soils become highly productive of Potatoes of the very finest quality. On the other hand, Potatoes also grow well on limestone and chalk, and yet there is but little lime in them. Here, again, mechanical texture explains the case in part, and it is further explained by the sufficiency of potash and phosphates, as also of magnesia, which enters in a special manner into the mineral constitution of this root. Thus far we have not even mentioned nitrogen, or its common form of salts of ammonia; nor have we mentioned carbon, or its very familiar form of carbonic acid. These are important elements of plant growth; and they account for the efficacy of manures derived directly from the animal kingdom, as, for example, the droppings of animals, including guano, which consisted originally of the droppings of sea-birds. Some of the nitrogen in these substances, however, is of an evanescent character, and rapidly flies away in the form of carbonate of ammonia; hence, a heap of farmyard manure, left for several years, loses much of its value as manure, and guano should be kept in bulk as long as possible, and protected from the atmosphere, or its ammonia will largely disappear. One difficulty experienced by chemists and others in preparing artificial manures is that of 'fixing' the needful ammonia, so that it may be kept from being dissipated in the atmosphere, and at the same time be always in a state in which it can be appropriated by the plant. In all good manures, however, there is a certain proportion of it in combination, and in many instances the percentage of nitrogen is made the test of the value of a manure. The importance of humus--the black earthy substance resulting from the decay of vegetation--in a soil is that it contains in an assimilable form many of the ingredients essential to plant life. Humus when it decomposes gives off carbonic acid, which breaks up the mineral substances in the soil and renders them available as plant food. When vegetable refuse is burned, the nitrogen--one of the costliest constituents--is dissipated and lost. But by burying the refuse the soil gets back a proportion of the organic nitrogen it surrendered and something over in the way of soluble phosphatic and potassic salts; and as this organic nitrogen assumes ultimately the form of nitric acid, it can be assimilated by the growing plant, to the great benefit of whatever crop may occupy the ground. The practical conclusion is, that in the treatment of the soil a skilful gardener will endeavour to promote its fertility by affording the natural influences of rain, frost and sun full opportunity of liberating the constituents that are locked up in the staple; by restoring in the form of refuse as much as possible of what the soil has parted with in vegetation; and by the addition of such fertilising agents as are adapted to rectify the natural deficiencies of the soil. Thus, instead of following a process of exhaustion, the resources of the garden may be annually augmented.

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